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1 article(s) from Kondo, Shin-ichi

Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen

Naoki Doi,
Yasushi Sasai,
Yukinori Yamauchi,
Tetsuo Adachi,
Masayuki Kuzuya and
Shin-ichi Kondo

Beilstein J. Org. Chem. 2017, 13, 1174–1183, doi:10.3762/bjoc.13.116

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Graphical Abstract

Figure 1: Structures of discrete mechanoradicals and the reaction sequence for their formation from cellulose ...

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Figure 2: Schematic structure of amylose, dextran and glycogen.

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Figure 3: Progressive changes in observed ESR spectra of fractured amylose [5], Dx, and Gly, together with simul...

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Figure 4: Schematic representation of bond cleavage at α-1,4- and α-1,6-bonds.

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Figure 5: ESR spectrum of fractured sample of Dx and TCNE (a) before and (b) after visible-light irradiation.

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Figure 6: Component spectra of the simulated ESR spectra.

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Figure 7: Progressive changes in the intensity of component spectra corresponding to the simulated spectra of...

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Figure 8: Changes in Dx molecular-weight distribution (MWD) during vibratory milling.

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Figure 9: Changes in Dx weight-average molecular weight (M_w) during vibratory milling.

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Figure 10: Change in Gly particle diameter during vibratory milling.

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Published 19 Jun 2017

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